Cr_2O_3对方镁石－尖晶石耐火材料抗渣性的影响

采用电熔镁砂及预合成电熔ＭＡ砂为原料，在高温下烧成方镁石－尖晶石试样，当加入少量铬矿时可提高其热震稳定性及抗渣性。用坩埚法作富ＣａＯ转炉渣对方镁石－尖晶石系耐火材料的侵蚀试验后，采用ＸＲＤ、ＳＥＭ、ＥＤＡＸ、岩相分析等方法分析Ｃｒ_２Ｏ_３对方镁石－尖晶石耐火材料抗渣性的影响。     

我国耐火材料矿物资源状况与发展问题的讨论

介绍了我国耐火资源的现状和开发利用状况,包括我国耐火资源储量分析、耐火资源的行业配置、耐火矿物资源消耗状况以及耐火矿物资源利用情况。对合理利用耐火资源,走可持续发展道路提出建议;通过改进原料产品生产工艺,提高耐火矿物资源的利用效能;合理使用耐火材料,降低耐火资源的消耗。     

低挥发分煤在新型干法窑生产中的应用

对劣质煤、低挥发分煤的燃烧特性分析,工艺设备分析,提出预分解窑烧劣质煤、低挥发分煤的可能性、必要性,为我公司烧劣质煤、无烟煤打下了基础。     

浅谈ZnO压敏电阻器低压化

近几十年来,国内外有关ZnO压敏电阻器低压化的研究报道很多。本文对低压化的方法作了较为系统的归类及评述,并对其发展趋势作了初步探讨。     

圆盘反应器中的PET缩聚过程

利用薄膜实验研究了PET缩聚过程反应和传质规律 ,建立了链增长、链降解反应动力学模型和泡沫脱挥时的传质速率方程 ;通过冷模实验研究了圆盘反应器中PET的混合、流动、成膜、膜表面更新以及传质规律 ;综合了反应和反应器研究结果 ,建立了圆盘反应器中的PET缩聚过程模型 ,对圆盘反应器中的PET缩聚过程进行了仿真分析 ,考察了温度、压力、停留时间、转速、催化剂浓度、负荷大小等各种因素的影响     

改性凹凸棒土净化含铬废水的研究

将凹凸棒土进行改性处理，用于对含铬废水中铬离子的吸附。本文研究了改性方式、凹凸棒土用量、吸附时间、pH值对含铬废水中铬离子净化率的影响。     

废弃木粉与短切玻璃纤维组合增强聚丙烯的力学性能

用废弃木粉与短切玻璃纤维作为增强材料，制得了组合增强的聚丙烯复合材料，研究了制备工艺及设备、材料配方及界面改性方法等对材料力学性能的影响。结果表明，用单螺杆挤出机制备组合增强材料，可减少对玻璃纤维的损伤，保持较长的玻璃纤维，有利于其增强作用的发挥；随着玻璃纤维含量的增加，体系的力学性能提高，而木粉含量对材料力学性能的影响与玻璃纤维的含量相关；采用硅烷偶联剂对木粉进行表面处理，在基体中添加接枝极性基团的改性聚丙烯，可改善体系的界面结合，提高力学性能。     

碳纤维片材加固钢筋混凝土梁的问题探讨

碳纤维片材加固钢筋混凝土梁的问题包括碳纤维片材加固钢筋混凝土梁的应用前提、钢筋混凝土梁斜向贴碳纤维抗剪加固承载力计算和使用阶段加固梁的验算公式。这些问题是对现行规范的补充和完善,并提出有待进一步研究的问题。     

Effect of nano‐silica filler on the rheological and morphological properties of polypropylene/liquid‐crystalline polymer blends

A fumed hydrophilic nano‐silica‐filled polypropylene (PP) composite was blended with a liquid‐crystalline polymer (LCP; Rodrun LC5000). The preblended polymer blend was extruded through a capillary die; this was followed by a series of rheological and morphological characterizations. The viscosity of the PP matrix increased with the addition of the hydrophilic nano‐silica. At shear rates between 50 and 200 s^?1, the composite displays marked shear‐thinning characteristics. However, the incorporation of LC5000 in the PP composite eliminated the shear‐thinning characteristic, which suggests that LC5000 destroyed the agglomerated nano‐silica network in the PP matrix. Although the viscosity ratio of LCP/PP was reduced after the addition of nano‐silica fillers, the LCP phases existed as droplets and ellipsoids. The nano‐silicas were concentrated in the LC5000 phase, which hindered the formation of LCP fibers when processed at high shear deformation. We carried out surface modification of the hydrophilic nano‐silica to investigate the effect of modified nano‐silica (M‐silica) on the morphology of the PP/LC5000 blend system. Ethanol was successfully grafted onto the nano‐silica surface with a controlled grafting ratio. The viscosity was reduced for PP filled with ethanol‐M‐silica when compared to the system filled with untreated hydrophilic nano‐silica. The LC5000 in the (PP/M‐silica)/LC5000 blend existed mainly in the form of fibrils. At high shear rates (e.g., 3000 s^?1), the LC5000 fibril network was formed at the skin region of the extrudates. The exclusion of nano‐silica in the LC5000 phase and the increased viscosity of the matrix were responsible for the morphological changes of the LCP phase. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1484–1492, 2003     

Self-assembly of C60 containing poly(methyl methacrylate) in ethyl acetate/decalin mixtures solvent

[60]Fullerene (C₆₀) was mono-substituted with well-defined poly(methyl methacrylate) (PMMA-b-C₆₀) using the atom transfer radical polymerization (ATRP) technique. The self-assembly behaviors of PMMA-b-C₆₀ in ethyl acetate (EA) and decalin mixtures were studied using laser light scattering (LLS) and transmission electron microscopy (TEM). Homogeneous solutions of PMMA-b-C₆₀ can be obtained in the solvent mixtures containing more than 40 wt% EA, where the molar ratio of decalin to EA is close to 1. For each solvent mixture, unimers coexist with micelles and large aggregates. The sizes of PMMA-b-C₆₀ micelles and aggregates are independent of polymer concentration, confirming that they are produced via the closed association mechanism. For the various solvent mixtures, the weight-averaged molecular weights, M_w of the PMMA-b-C₆₀ aggregates range from 4.1×10⁷ to 12.5×10⁷ g/mol. The hydrodynamic radii of the large aggregate, R_h, vary from 90 to 136 nm, while the z-averaged radii of gyration, R_g, range from 210 to 311 nm. The R_g/R_h value for each solvent mixture is ∼2.3, which is independent of decalin contents in the mixed solvents. The morphological study using the transmission electron microscope suggests that the large aggregates are composed of porous large compound micelles (LCM) in solution.